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Figure 5.15 The Bohr radius A as a function of well width for donors at the centres of GaAs wells surrounded by Gao.gAlo.iAs barriers

The process by which one infers an invariant property from a set of observations is called inductive reasoning. Induction, as opposed to deduction, is about abstracting general laws from specific instances. It is a process that is vital to the progress of science.

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5.5 VARIABLE-SYMMETRY TRIAL WAVE FUNCTION In the two previous sections, simple high-symmetry trial wave functions have been chosen to illustrate the method. Indeed, often they provide approximate, but quick, numerical results that may generally suffice. However, a little thought highlights their deficiencies. The aim of this work, like the solution of many physical systems with the variational principle, is to choose a trial wave function which is applicable no matter what the system parameters may be. Which in this case would mean, no matter what the well width, barrier height and donor position are. The spherical 3D trial wave function was chosen as this is the form found in bulk materials, i.e. systems which do not have a confining potential. Hence it might be expected that this trial wave function is most appropriate for systems which most closely resemble bulk systems i.e. those with only small confinement, such as wide wells and/or low barrier heights. For example, for a donor in the centre of a wide well, the envelope x(z) would look like cos kz, which would be slowly varying, and hence the total wave function u would resemble the bulk. Conversely, a large confinement potential might be expected to give a more 2D-like wave function. It is clear, therefore that while the two trial wave functions considered so far are useful, a more general form can be taken for the hydrogenic factor, a variable symmetry term, which can move between the 2D and 3D forms should it prove energetically favourable to do so. Equation (5.94) summarizes the most general choice for the hydrogenic factor of the trial wave function:

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cTOn Cz dk,p(zp,Uk) T drs nk(t) hmn,kj j J k K kj Kk,p(t) set Afc k-th mn nr, ns Nmn o(t) a(t) uk Wkj

Induction proceeds from observation to conjectures to proof. Conjectures that are proved become laws. For example, we may observe that 1 = I 2 , 1 + 3 = 2 2 , 1 +- 3 + 5 = 32 and 1 + 3 + 5 + 7 = 4 2 . We recognize a pattern and so make the conjecture that

Figure 5.16 Schematic illustration of the variable symmetry relative motion term in the donor trial wave function

1 + 3+ ... +(2m = (m + 1)

where C is a second variational parameter, which like A will be adjusted systematically in order to minimize the total energy E of the system. Hence:

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map coordinates of the BMN input covariance matrix Euclidean distance between input vector zp and weight vector quantization error on training set Ward distance between clusters r and s time-varying learning rate for output unit Ok neighborhood function for neuron mn SOM column index total number of columns in SOM SOM row index total number of rows in SOM index of a SOM neuron of neighbors of winning cluster ok for pattern p eigenvalue index of the BMN number of patterns within clusters r and 5 respectively number of patterns for which neuron mn is the BMN vector of output values at time step t time-varying width of Gaussian function vector of weights leading to output unit o^ weight vector of SOM neuron kj weight vector changes for SOM neuron kj weight value from input Zj for neuron kj centroid vector of clusters r and s respectively p-th input vector input matrix

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